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to v or not to v |
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 to v or not to v World Chat Champion

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xX-Alex-Xx |
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 xX-Alex-Xx World Chat Champion
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Copycat73 |
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 Copycat73 World Chat Champion

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MarJay |
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 MarJay But it's British!

Joined: 15 Sep 2003 Karma :     
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 Posted: 12:46 - 26 Jun 2021 Post subject: |
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It's not as simple as that. Your question implies a binary state that does not exist.
Petrol is not one homologous substance. It's not pure Octane or whatever. Petrol is a blend of hydrocarbons from hexane, to octane to all sorts of chains of C and H together, as well as some ethanol these days (up tp 5% but soon to be up to 10% Yikes). The reason it goes 'off' is because some of the elements of that blend are more volatile than others. By volatile, I mean that in the chemistry sense, not in the general use sense. It doesn't mean it might throw the crockery across the room and run away with the postman, what it means is that it naturally vapourises at room temperature. There is a % probability of it being vapour at room temperature, and different volatility levels mean a different percentage and all that chemistry malarkey.
So, what that means is that some of the blend vapourises, leaving behind the more stable parts. In a motorcycle, car or other vehicle you cannot have buildup of vapour due to safety issues related to pressure and flammability or explosiveness. Hence why there are breather pipes on fuel tanks. In that case, if fuel is left in a car or bike, the volatile parts of the fuel will vapourise and leave the tank via the breather. The downside of that of course is the volatile parts are the parts that burn easily, meaning the sludge you're left with after a long time is not very good as a fuel.
In a Jerry can or Green plastic fuel can, the vapour can't escape. The changes in temperature etc would mean the vapour could return back to a liquid state, and in reality this process is basically happening all the time. So, if you keep the fuel in a sealed can, and make sure it's agitated enough when you go to use it it should be OK.
This does not preserve the fuel indefinitely, but it will increase the shelf life by a LOT. So, your premise that the short shelf life of fuel is exaggerated is in fact incorrect.
Then there's the other additives such as stabilisers, detergents, ethanol etc... that's a whole 'nother can of worms and that's usually the stuff that leaves the 'glue' behind when the fuel has completely vapourised. ____________________ British beauty: Triumph Street Triple R; Loony stroker: KR1S; Track fun: GSXR750 L1; Commuter Missile: GSX-S1000F
Remember kids, bikes aren't like lego. You can't easily take a part from one bike and then fit it to another. |
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stinkwheel |
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 stinkwheel Bovine Proctologist

Joined: 12 Jul 2004 Karma :    
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chickenstrip |
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 chickenstrip Super Spammer

Joined: 06 Dec 2013 Karma :    
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 Posted: 14:07 - 26 Jun 2021 Post subject: |
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MarJay wrote: | It's not as simple as that. Your question implies a binary state that does not exist.
Petrol is not one homologous substance. It's not pure Octane or whatever. Petrol is a blend of hydrocarbons from hexane, to octane to all sorts of chains of C and H together, as well as some ethanol these days (up tp 5% but soon to be up to 10% Yikes). The reason it goes 'off' is because some of the elements of that blend are more volatile than others. By volatile, I mean that in the chemistry sense, not in the general use sense. It doesn't mean it might throw the crockery across the room and run away with the postman, what it means is that it naturally vapourises at room temperature. There is a % probability of it being vapour at room temperature, and different volatility levels mean a different percentage and all that chemistry malarkey.
So, what that means is that some of the blend vapourises, leaving behind the more stable parts. In a motorcycle, car or other vehicle you cannot have buildup of vapour due to safety issues related to pressure and flammability or explosiveness. Hence why there are breather pipes on fuel tanks. In that case, if fuel is left in a car or bike, the volatile parts of the fuel will vapourise and leave the tank via the breather. The downside of that of course is the volatile parts are the parts that burn easily, meaning the sludge you're left with after a long time is not very good as a fuel.
In a Jerry can or Green plastic fuel can, the vapour can't escape. The changes in temperature etc would mean the vapour could return back to a liquid state, and in reality this process is basically happening all the time. So, if you keep the fuel in a sealed can, and make sure it's agitated enough when you go to use it it should be OK.
This does not preserve the fuel indefinitely, but it will increase the shelf life by a LOT. So, your premise that the short shelf life of fuel is exaggerated is in fact incorrect.
Then there's the other additives such as stabilisers, detergents, ethanol etc... that's a whole 'nother can of worms and that's usually the stuff that leaves the 'glue' behind when the fuel has completely vapourised. |
Nicely explained, but I particularly love the bit I've highlighted
Tsk chickenstrip, can't you be serious for just one minute?!  ____________________ Chickenystripgeezer's Biking Life (Latest update 19/10/18) Belgium, France, Italy, Austria tour 2016 Picos de Europa, Pyrenees and French Alps tour 2017 Scotland Trip 1, now with BONUS FEATURE edit, 5/10/19, on page 2 Scotland Trip 2 Luxembourg, Black Forest, Switzerland, Vosges Trip 2017
THERE'S MILLIONS OF CHICKENSTRIPS OUT THERE! |
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jeffyjeff |
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 jeffyjeff World Chat Champion

Joined: 02 May 2020 Karma :   
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 Posted: 15:05 - 26 Jun 2021 Post subject: |
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To Marjay's point, the lighter constituents in the fuel that vapourise most readily are the same ones that promote easy starting and smooth running in cold temperature. The lightest ones are propane and butane, to my recollection. You would likely notice their absence more readily if you were trying to start your motor in sub zero temperatures.  ____________________ History shows again and again how nature points out the folly of men - BOC |
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doggone |
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 doggone World Chat Champion

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Blah blah |
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 Blah blah Scooby Slapper
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to v or not to v |
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 to v or not to v World Chat Champion

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MCN |
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 Blah blah Scooby Slapper
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MarJay |
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 MarJay But it's British!

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MCN |
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 MCN Super Spammer

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to v or not to v |
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 to v or not to v World Chat Champion

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MCN |
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 MCN Super Spammer

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 iooi Super Spammer

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A100man |
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 A100man World Chat Champion

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 Posted: 11:47 - 28 Jun 2021 Post subject: |
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Yeah, can't say I've had a lot of trouble with 'stale' fuel to date in spite of the doom mongers.
Moving to 10% booze though might prove a different story. Makes me wonder - where does it all come from? In Brazil it's brewed up from sugar cane isn't it? ____________________ Now: A100, GT250A, XJ598, FZ750
Then: Fizz, RS200, KL250, XJ550, Laverda Alpina, XJ600, FZS600 |
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Robby |
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 Robby Dirty Old Man

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Kawasaki Jimbo |
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 Kawasaki Jimbo World Chat Champion

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Kawasaki Jimbo |
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 Kawasaki Jimbo World Chat Champion

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 Robby Dirty Old Man

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 Kawasaki Jimbo World Chat Champion

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Robby |
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 Robby Dirty Old Man

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MCN |
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 MCN Super Spammer

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 Posted: 01:58 - 30 Jun 2021 Post subject: |
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Robby wrote: | Aviation is a big driver for biofuels from people that want to sell biofuels. It's a big thing for the airline industry to talk about wanting to do (lots of hand wringing), but not being able to do because safety. I was intimately involved in this a few years back.
Early tests were carried out about 10-15 years ago using biofuel in airliners. Never got any further. Turns out that people who care about emissions from aviation just try to avoid flying altogether, and governments around the world can't even get a decent amount of tax on aviation fuel, let alone force airlines to use biofuel.
The main issue is safety. Airlines will only trust biofuel after millions of miles flown on it and thousands of inspections, particularly looking for any evidence of mould or icing in the fuel system. No-one wants to pay for this, and by the time it gets anywhere near reality battery tech should be giving us electric airliners, at least for short haul. So a risky investment with a lot of push back.
Still, I'm hoping that airlines may get a bit more co-operative post covid, assuming passengers numbers stay below their pre-pandemic levels and a few companies go bust. Tends to focus the minds of the remaining ones to stop pissing off governments, and treat your passengers a lot better. |
Yep, avgas and Jet A B are clean enough to drink.
Head ache to maintain in a tank and dispensing equipment is like hospital hygiene clean.
Hydroscopic properties of ethanol is the deal. ____________________ Disclaimer: The comments above may be predicted text and not necessarily the opinion of MCN. |
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Old Thread Alert!
The last post was made 4 years, 31 days ago. Instead of replying here, would creating a new thread be more useful? |
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