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Whats difference between semi synthetic and full synthetic

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HardDriver
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PostPosted: 21:40 - 17 Apr 2014    Post subject: Whats difference between semi synthetic and full synthetic Reply with quote

Hi guys. As you can see of this post topic, I want to now differences between these oils? What benefits have semi and what full? What about longevity? Is it true, that synthetic oil is designed with improved lubricate properties and enhanced viscosity to provide superior protection from engine wear, reduced heat breakdown volatility for decreased oil consumption, improved fuel mileage, easier engine cold starting and a reduction in engine deposits.

What minuses have semi? How long could you use this oil (when did he change his structure)? Is it true, fully synthetic oils are not really necessary unless you have a high-powered sports/luxury car or an engine with significant performance upgrades (highly tuned). Obviously engines that are subject to high stress levels (like supercars or motorsport machines) need the best protection available, so it makes sense to splash out for the finest oil. But the majority of road going cars are not highly stressed or severely punished on a regular basis, so semi-synthetic is more than adequate. One more thing, I heard also, that they are same, but interval (when they change structure) for fully is longer, for semi not?

Is it true, that fully synthetic have lighter viscosity (slippy Very Happy) (if I take both 10w40) and semi harder?

Thanks for comments. I need to change my oil and I don't know what should I use?


Also, I need to change gear oil, it's SAE85w90 or SAE90w90. Isn't these oils rare? What should I use? Can I use not recommended oil? Will be really bad?
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Fisty
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PostPosted: 21:46 - 17 Apr 2014    Post subject: Reply with quote

Not sure if serious.
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MarJay
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PostPosted: 21:48 - 17 Apr 2014    Post subject: Reply with quote

Have you just copied the blurb from the back of an oil bottle into BCF? Confused
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Chalky.
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PostPosted: 21:50 - 17 Apr 2014    Post subject: Reply with quote

Semi synthetic is equivalent to half of a full synthetic.

Sometimes it is better to run the engine at double the normal level with semi synth. I've run engines half full with fully synthetic too though to save money - cost of oil halves.
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HardDriver
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PostPosted: 21:52 - 17 Apr 2014    Post subject: Reply with quote

MarJay wrote:
Have you just copied the blurb from the back of an oil bottle into BCF? Confused


No, I just found some information on the internet. Lots of information, but what I want was not answer my questions.

And one thing, which company make the better oils or COMPANIES for motorcycle? Like motul and so one?
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HardDriver
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PostPosted: 21:52 - 17 Apr 2014    Post subject: Reply with quote

MarJay wrote:
Have you just copied the blurb from the back of an oil bottle into BCF? Confused


No, I just found some information on the internet. Lots of information, but what I want was not answer my questions.

And one thing, which company make the better oils or COMPANIES for motorcycle? Like motul and so one?
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Fisty
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PostPosted: 21:53 - 17 Apr 2014    Post subject: Reply with quote

Chalky. wrote:
Semi synthetic is equivalent to half of a full synthetic.

Sometimes it is better to run the engine at double the normal level with semi synth. I've run engines half full with fully synthetic too though to save money - cost of oil halves.


I ran my bike with a semi once, it was very uncomfortable against the tank.
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Tamsin
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PostPosted: 21:56 - 17 Apr 2014    Post subject: Reply with quote

Semi-Syth is 50% mineral oil (i.e what they drill out of the ground) and 50% synthesised in a lab.

Synthetic is totally manufactured - none of that stuff they drill out.

as to what to put in your bike and when to change it? RTFM
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mentalboy
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PostPosted: 22:01 - 17 Apr 2014    Post subject: Reply with quote

Fisty wrote:


I ran my bike with a semi once, it was very uncomfortable against the tank.


Which brand of synthetic were you using, I believe cheaper ones can be uncomfortable. Did you half fill it?
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HardDriver
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PostPosted: 22:01 - 17 Apr 2014    Post subject: Reply with quote

Yeagh, I know that, thanks for posts. If someone knows answers for my questions, please tell me. Ignorance killing me Very Happy.
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Kickstart
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PostPosted: 22:03 - 17 Apr 2014    Post subject: Reply with quote

Hi

My understanding is that oil itself doesn't wear out, rather the additive packages do. Synthetic oils need less additives to get a wide viscosity range. Hence less of the bit that wears out and they last longer.

But still full of the rubbish that gets last the rings, etc.

All the best

Keith
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lihp
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PostPosted: 22:48 - 17 Apr 2014    Post subject: Reply with quote

MissTamsin wrote:
Semi-Syth is 50% mineral oil (i.e what they drill out of the ground) and 50% synthesised in a lab.

Synthetic is totally manufactured - none of that stuff they drill out.

as to what to put in your bike and when to change it? RTFM


Wrong, fully synthetic, semi-synth, and mineral oil all still come from the same crude oil. The difference is the level of additive in the oil.
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Teflon-Mike
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PostPosted: 22:51 - 17 Apr 2014    Post subject: Reply with quote

MissTamsin wrote:
Semi-Syth is 50% mineral oil (i.e what they drill out of the ground)

Err... no, what comes out he ground is called 'crude' oil.
Have you ever seen any?
My Uncle used to work on the oil rigs; he brought a Jam Jar of the stuff home once. Its like treacle! You could lift it out of the jar with a fork!

They make a whole range of 'products' from the stuff; basically they boil it up, and the lighter fractions evaporate off first,. and they distill them; that gives you petrol; then diesel, then I think Kerosene, then you start getting 'light oils' like sewing machine oil, then they start getting thicker, through lubricating oils, and greases, until you get to the gunk at the bottom.

They then process these base fractions, with other chemicals, to make the products we buy, like petrol or diesel or grease or engine oil.

MissTamsin wrote:
Synthetic is totally manufactured


Its all 'manufactured' but synthetic oils are more 're-manufactured'. Rather than blending basic distilates from the crude and adding other ingredients, to make a 'mineral engine oil', they chemically 'crack' the long chain hydrocarbon molecules to simpler compounds, then chemically reconstruct them; to get more consistent properties.

So Semi-Synth is a 'blend' of more conventional mineral oil with 'some' chemically engineered synthetic oil in it.

Whether synthetic oil is any 'better' than blended mineral oil?

Are two-strokes better than four-strokes? Its horses for courses. But then marketing men will always try and get you to pay for something you don't really need if they can, and they seem to like selling oil.

I go by manufacturers recomendation; they ought to know what's best for the engine's they build; and just get the cheapest that meets that spec that I can.
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Tamsin
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PostPosted: 22:58 - 17 Apr 2014    Post subject: Reply with quote

Teflon-Mike wrote:
MissTamsin wrote:
Semi-Syth is 50% mineral oil (i.e what they drill out of the ground)

Err... no, what comes out he ground is called 'crude' oil.
Have you ever seen any?
My Uncle used to work on the oil rigs; he brought a Jam Jar of the stuff home once. Its like treacle! You could lift it out of the jar with a fork!


I was going really over simplified as seemed to be required based on the original post. Its been quite a while since I did my chemistry GCSE but I'm fully aware of how fractionation towers work and somewhat familiar with the hydrocarbon products that are produced.

I wasn't for one minute sticking crude oil into an engine Laughing
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weasley
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PostPosted: 09:47 - 18 Apr 2014    Post subject: Reply with quote

So much waffle in one post.

An engine oil is made of base oils and additives. The base oils are the major part, comprising around 80-ish percent of the formulation (give or take, depending on the specific needs). The overal description "mineral", or "synthetic" etc refers only to the source of the base oils. The remaining 20% is a mix of additives to enhance or modify the performance of the base oils. The additives can be natural or synthetic, and are usually diluted in mineral base oil to make them easy to handle.

The term "semi-synthetic" has no specific basis in law or any other regulation. It refers to an oil with a mixture of some part mineral oil and some part synthetic. It does not have to be (and is rarely) 50:50. It could be as low as 20% or as high as 80% synthetic. Other terms like "part-synthetic" or "synthetic-enhanced" are also common.

In general terms, the higher the % of synthetic, the higher the overall performance. Using better base oil can also mean you don't have to add as much additive.

Mineral oil is refined from crude oil, from where it is distilled and then impurities extracted by solvent washing and other treatments.

Synthetic oil is either:

1. Taken from crude oil, as above, but then treated in a hydrocracker to chemically alter the molecules to eliminate unhelpful ones and create good ones

2. Synthesised from scratch using ethylene gas molecules as a building block to make long chain molecules. The gas comes from the refinery by the way, so this came out of the ground too. This type is known as polyalphaolefin, or PAO.

3. Other types are made by chemical reactions, such as esters and polyglycols.

An oil "wears out" though a number of mechanisms. Some additives become exhausted in use as they do their job, meaning you have to change the oil to refresh them. The base oils do get affected too, by oxidation, which causes them to polymerise and get thicker, as well as forming acidic species which can be corrosive. The viscosity-controlling polymers added to oil also get broken up by shearing effects, which reduces their effect and causes the oil to thin out at high temperatures. Finally, the oil collects contamination as it goes along which eventually reaches a level that the oil can't hold and needs to be changed. Some of the oil 'boils' away in the engine too, which is generally why the level drops over time and you need to top up. Remember, topping up is good not only to get the level of oil up but also because it adds a shot of fresh additives.

Also, crude oil can look anything from treacle to black water, depending where you get it.
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arry
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PostPosted: 09:54 - 18 Apr 2014    Post subject: Reply with quote

It gets further complicate by some synthetic oils not actually being fully synthetic but a hydrocracked semi

The main advantage as I understand it is that ester oils are much more resistant to shear which means they can handle more abuse in respect of high temperature
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weasley
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PostPosted: 10:08 - 18 Apr 2014    Post subject: Reply with quote

arry wrote:
It gets further complicate by some synthetic oils not actually being fully synthetic but a hydrocracked semi

The main advantage as I understand it is that ester oils are much more resistant to shear which means they can handle more abuse in respect of high temperature


I described the hydrocracked oils in point 1 above. They are still synthetic and not and never have been "semi" anything.

Esters are very good base oils but are eye-wateringly expensive and if they are used are only ever used as a supplement to other base oils.
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arry
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PostPosted: 10:15 - 18 Apr 2014    Post subject: Reply with quote

Interesting, thanks.

Are the likes of Silkolene Pro S fully ester or just part ester?
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Polarbear
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PostPosted: 10:50 - 18 Apr 2014    Post subject: Reply with quote

weasley wrote:
arry wrote:
It gets further complicate by some synthetic oils not actually being fully synthetic but a hydrocracked semi

The main advantage as I understand it is that ester oils are much more resistant to shear which means they can handle more abuse in respect of high temperature


I described the hydrocracked oils in point 1 above. They are still synthetic and not and never have been "semi" anything.

Esters are very good base oils but are eye-wateringly expensive and if they are used are only ever used as a supplement to other base oils.


We are having to use ester based oils in ships that go to yank land as they created to break down when in the sea. Called EAL oils (Environmentally Aware Lubricants) they are diabolically expensive, basically 10 times the price of a standard mineral based oil so when the powers that be decide all oils have to be environmentally friendly get ready to be bummed Rolling Eyes
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weasley
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PostPosted: 13:30 - 18 Apr 2014    Post subject: Reply with quote

Polarbear wrote:
[We are having to use ester based oils in ships that go to yank land as they created to break down when in the sea. Called EAL oils (Environmentally Aware Lubricants) they are diabolically expensive, basically 10 times the price of a standard mineral based oil so when the powers that be decide all oils have to be environmentally friendly get ready to be bummed Rolling Eyes


Yes, there are some specialist oils that will use esters (and other base oils) for particular reasons.

Silkolene Pro S and other ester-containing oils will be ester-fortified, probably in conjunction with PAO and/or a hydrocracked or mineral oil.

One down-side of PAO is that additives have limited solubility in it, since PAO is highly aliphatic and many additives have polar components. Esters introduce some polarity to the base oil and make solubility easier.

Esters also offer electrostatic attraction to metal surfaces, which at least one manufacturer has made a prominent part of their product claims. That said, most of the additives are also surface active so competition for the surface can be quite complex.
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Pete.
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PostPosted: 17:06 - 18 Apr 2014    Post subject: Reply with quote

Semi synthetic will always beat fully synthetic in a scrap. Fully synthetic just ain't got the minerals...
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