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Homebrew version of hammerite rust remover dip ?

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Ribenapigeon
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PostPosted: 14:11 - 01 Feb 2015    Post subject: Homebrew version of hammerite rust remover dip ? Reply with quote

I bought some hammerite rust remover dip to get the rust off some tools in restoring. It works fine but is pricey. Is there a homebrew version? There's no clue on the bottle as to the active ingredients.

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barrkel
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PostPosted: 14:16 - 01 Feb 2015    Post subject: Reply with quote

Active ingredient is probably an acid. There's lots of articles on the web about using various acids to remove rust.

Of course, there's other techniques, like electrolysis.
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MarJay
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PostPosted: 14:36 - 01 Feb 2015    Post subject: Reply with quote

I think there is some rather complex chemistry involving chelation and stuff like that, I doubt you could make some at home.
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Ribenapigeon
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PostPosted: 15:26 - 01 Feb 2015    Post subject: Reply with quote

I just cleaned up a piece after soaking it overnight. Its worked well. Something I noticed was a steel part had taken on some copper colour as if plated. Part of the thing I dipped is brass. So some sort of electrolytic process has occurred. If the solution is an acid would that have created copper salts then some potential difference between the brass and steel caused some electroplating?
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DrSnoosnoo
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PostPosted: 16:02 - 01 Feb 2015    Post subject: Reply with quote

Coca cola works well. Just soak shit in that. Carbonic acid knocks about which can work to get the rust away. In the hammerite gear, the stuff that turns rust black is apparently phosphoric acid.
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stinkwheel
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PostPosted: 17:29 - 01 Feb 2015    Post subject: Reply with quote

Strong hydrochloric acid, (also marketed as spirit of salts) will remove rust (and dissolve metal).

Hot, strong phosphoric acid will remove rust and black anodise bare metal.

Electrolysis will loosen/remove rust very effectively but not in the way you think it does.

If you had something pretty rusty, you could do them one after the other. So electrolysis then HCl then Phosphoric acid.

A mate of mine pulled a rusty sidecar chassis out of a river estury. He did it in an electrolysis bath. Went from this:
https://www.ratbike.org/aarrgghh/SSOD/pic_0501.jpg

To this:
https://www.ratbike.org/aarrgghh/SSOD/Detail2.jpg
https://www.ratbike.org/aarrgghh/SSOD/Detail1.jpg
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barrkel
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PostPosted: 17:35 - 01 Feb 2015    Post subject: Reply with quote

snoosnoo wrote:
Coca cola works well. Just soak shit in that. Carbonic acid knocks about which can work to get the rust away. In the hammerite gear, the stuff that turns rust black is apparently phosphoric acid.

Carbonic acid is fizzy water - it's carbon dioxide dissolved in water. Coke also contains phosphoric acid. Soaking in coke, you're relying more on the latter than the former.
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PostPosted: 17:47 - 01 Feb 2015    Post subject: Reply with quote

Go for the electrolysis option. You'll most likely have nearly all the stuff needs lying about anyway and it's pretty much set up and forget and really does work.
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Ribenapigeon
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PostPosted: 17:55 - 01 Feb 2015    Post subject: Reply with quote

how do you homebrew electrolysis?
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Moo.
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PostPosted: 17:59 - 01 Feb 2015    Post subject: Reply with quote

Electrolysis is a bit fiddly, but for sit back a watch...

Look up Molasses rust removal.

Basically dissolve 1 part molasses sugar to 10 parts water, takes aaaages to soak, but its dirty cheap (£1.19 per 500g) forms an acidic solution which eats away...

If you want good results and are willing to spend a bit, look up Deox-C gel or crystals, made by a company called Bilt Hamber. Good results

Most acids will form salts on the surface of the metal afterwards though, these salts attract water, so if its not treated soon (painting, or rust protection) there will be surface rust soon..
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PostPosted: 18:17 - 01 Feb 2015    Post subject: Reply with quote

Boozehawk wrote:
how do you homebrew electrolysis?


Here
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Ribenapigeon
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PostPosted: 18:29 - 01 Feb 2015    Post subject: Reply with quote

Moo. wrote:
Electrolysis is a bit fiddly, but for sit back a watch...

Look up Molasses rust removal.

Basically dissolve 1 part molasses sugar to 10 parts water, takes aaaages to soak, but its dirty cheap (£1.19 per 500g) forms an acidic solution which eats away...

If you want good results and are willing to spend a bit, look up Deox-C gel or crystals, made by a company called Bilt Hamber. Good results

Most acids will form salts on the surface of the metal afterwards though, these salts attract water, so if its not treated soon (painting, or rust protection) there will be surface rust soon..


Bloody amazing https://m.youtube.com/watch?v=vq5IUiYMhRM
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DrSnoosnoo
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PostPosted: 18:39 - 01 Feb 2015    Post subject: Reply with quote

barrkel wrote:
snoosnoo wrote:
Coca cola works well. Just soak shit in that. Carbonic acid knocks about which can work to get the rust away. In the hammerite gear, the stuff that turns rust black is apparently phosphoric acid.

Carbonic acid is fizzy water - it's carbon dioxide dissolved in water. Coke also contains phosphoric acid. Soaking in coke, you're relying more on the latter than the former.


The amount of carbon dioxide dissolved in the water would give a high amount of this fizzy water, how much phosphoric acid do you propose is in coke?
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barrkel
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PostPosted: 19:16 - 01 Feb 2015    Post subject: Reply with quote

snoosnoo wrote:
The amount of carbon dioxide dissolved in the water would give a high amount of this fizzy water, how much phosphoric acid do you propose is in coke?

This Q&A looks interesting and relevant: https://chemistry.stackexchange.com/questions/2859/what-makes-coke-acidic

It seems there's not 100% agreement on whether the acidity is mostly carbonic or phosphoric acid. It would be great if we had a higher authority than a student's experiment to go on.

However, this wouldn't be relevant in practice. Use coke in a non-pressurized bath for anything with as many nucleation sites for bubbles as rusty metal, and it will be flat in short order. Then you'll be relying on the phosphoric acid.
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DrSnoosnoo
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PostPosted: 19:59 - 01 Feb 2015    Post subject: Reply with quote

barrkel wrote:
This Q&A looks interesting and relevant: https://chemistry.stackexchange.com/questions/2859/what-makes-coke-acidic

It seems there's not 100% agreement on whether the acidity is mostly carbonic or phosphoric acid. It would be great if we had a higher authority than a student's experiment to go on.

However, this wouldn't be relevant in practice. Use coke in a non-pressurized bath for anything with as many nucleation sites for bubbles as rusty metal, and it will be flat in short order. Then you'll be relying on the phosphoric acid.


It wasn't too long ago that I tried to find a declared level of phosphoric acid in coke but, hey, it's what helps their flavour so they don't go shouting about it.
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Ribenapigeon
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PostPosted: 20:46 - 01 Feb 2015    Post subject: Reply with quote

barrkel wrote:
snoosnoo wrote:
The amount of carbon dioxide dissolved in the water would give a high amount of this fizzy water, how much phosphoric acid do you propose is in coke?

This Q&A looks interesting and relevant: https://chemistry.stackexchange.com/questions/2859/what-makes-coke-acidic

It seems there's not 100% agreement on whether the acidity is mostly carbonic or phosphoric acid. It would be great if we had a higher authority than a student's experiment to go on.

However, this wouldn't be relevant in practice. Use coke in a non-pressurized bath for anything with as many nucleation sites for bubbles as rusty metal, and it will be flat in short order. Then you'll be relying on the phosphoric acid.


What if you kept carbonating it with a soda stream type arrangement?
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bikenut
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PostPosted: 11:38 - 02 Feb 2015    Post subject: rust Reply with quote

have heard that lemon juice is quite good.......used on the nazi fighter plane in cosford, from the channel..........

will post an article from a mag about home electrolysis......

phosphoric acid is in coke....also Jenolite rust remover........

carbonic acid ( as well as sulphuric and other stuff no doubt ) is in rain fall, acid rain.......
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bikenut
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PostPosted: 11:43 - 02 Feb 2015    Post subject: Reply with quote

TheBaldRevere...
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PostPosted: 18:17 - 01 Feb 2015 Post subject: Reply with quote




Boozehawk wrote:

how do you homebrew electrolysis?



Here

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that's the one, article shows rusty mess, the rust removed.......says it leaves the clean article with a black patena coating.......

now to find home electroplating stuff in tin.........or copper...... Karma
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